Abstract Ligand‐promoted copper‐catalyzed cascade reactions have become a robust tool for the synthesis of cyclic compounds. Although numerous ligands have been developed, this review focuses on the introduction of commercially available 1,10‐phenanthroline‐promoted copper‐catalyzed cascade reactions in recent years.

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Acute Tox. 3 Aquatic Acute 1 Aquatic Chronic 1. HP6 Acute Toxicity: waste which can cause acute toxic effects following oral 1,10-Phenantroline | Sigma-Aldrich. Search results for 1,10-Phenantroline at Sigma-Aldrich. ADVANCED SEARCH. STRUCTURE SEARCH. CERT OF ANALYSIS. SDS SEARCH.

1 10-phenanthroline

1, 10-Phenanthroline monohydrate. For research use only. 1,10- Phenanthroline is a classic chelating bidentate ligand for transition metal ions that has played an 1,10-Phenanthroline inhibits the metallopeptidase secreted by Phialophora verrucosa and modulates its growth, morphology and differentiation. Mycopathologia 1,10-Phenanthroline monohydrate. Formula: C12H8N2 • H2O. MW: 198.22 g/mol . Storage/Handling: Store desiccated at room temperature under inert gas. Danger!

Terfenadine The therapeutic efficacy of Terfenadine can be decreased when used in combination with 1,10-Phenanthroline. 1,10-Phenanthroline là chất ức chế metallicopeptidase, với một trong những trường hợp quan sát đầu tiên được báo cáo trong carboxypeptidase A. Sự ức chế enzyme xảy ra bằng cách loại bỏ và thải ion kim loại cần thiết cho hoạt động xúc tác, để lại một apoenzyme không hoạt động.

It is inhibited by bacitracin, chelating agents EDTA and 1,10-phenanthroline, and by thiol-blocking reagents such as N-ethylmaleimide, but not phosphoramidon.

1,10-Phenanthroline là chất ức chế metallicopeptidase, với một trong những trường hợp quan sát đầu tiên được báo cáo trong carboxypeptidase A. Sự ức chế enzyme xảy ra bằng cách loại bỏ và thải ion kim loại cần thiết cho hoạt động xúc tác, để lại một apoenzyme không hoạt động. 1,10-Phenanthroline nhắm mục tiêu chủ yếu là kẽm metallicopeptidase, với ái lực thấp hơn nhiều đối với canxi. Chemsrc provides 1,10-Phenanthroline-5,6-dione(CAS#:27318-90-7) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc.

NB: Registration status and tonnage. The REACH Registered substance portal was updated on 9th November 2020; the REACH registered

For non-emergency personnel A phenanthroline ligand refers to a ligand having a phenanthroline ring in its molecular structure. 1,10-phenanthroline has a planar rigid structure and plays an important role in coordination chemistry; its two adjacent atoms can form a feedback bond with many transition metals, resulting in a stable complex, which is important in many fields. The first metal complex demonstrated to cleave DNA was the 1,10-phenanthroline–cuprous ion complex ((OP) 2 Cu +) (3), reported by Sigman and co-workers. 66 (OP) 2 Cu + binds to DNA in the minor groove, and in the presence of hydrogen peroxide generates a metal-associated hydroxyl radical-like species, leading to attack at the C-1′ or C-4′ positions of deoxyribose and subsequent backbone scission (for reviews, see Sigman and Chen 27 and Sigman et al.28). 1,10-Phenanthroline (anhydrous) for synthesis. CAS 66-71-7, molar mass 180.21 g/mol. 1,10-Phenanthroline MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Molecular Formula: C20H24N2, MW: 292.43. CAS: 54258-41-2 MDL: MFCD00455733. ligands with 1,10-phenanthroline or 2,2′-bipyridyl leads to an increase in the rate of exchange in the manganese complexes, from k298 (1.8 ± 0.1) × 107 s-1 Substitution of aquo ligands with 1,10-phenanthroline or 2,2′-bipyridyl leads to an increase in the rate of exchange in the manganese complexes, from k298 NB: Registration status and tonnage. The REACH Registered substance portal was updated on 9th November 2020; the REACH registered Europeiska kemikaliemyndigheten (nedan kallad Echa) förvaltar denna webbplats (nedan kallad Echas webbplats) i syfte att förbättra allmänhetens tillgång till X-ray structures are presented of three new cobalt complexes prepared from Co(III) and N,N'-1,10-phenanthroline-5,6-dione. The cis-aqua-chloro-bis(N,N'-1 1,10-Phenanthroline hydrochloride monohydrate.
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VIEW ALL SEARCH RESULTS. Type in Product Names, Product Numbers, or CAS Numbers to see suggestions. 1,10-Phenanthroline, Monohydrate, ACS (5144-89-8) LD50 oral rat 132 mg/kg (Rat, Oral) ATE US (oral) 132 mg/kg body weight . Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Phenanthroline is 1,10-phenanthroline. A phenanthroline ligand refers to a ligand having a phenanthroline ring in its molecular structure.

For convenience, this compound will be abbreviated 1,10-phen throughout the remainder of this text. Since CAS RN:52698-84-7 Product grade:Special Reagent for specific use Application: for metal colorimetric determination. Supplier:NACALAI TESQUE, INC. Other articles where Ferrous 1,10-phenanthroline is discussed: chemical indicator: Ferrous 1,10-phenanthroline, an oxidation-reduction indicator, changes from 13 Jun 2005 1,10-Phenanthroline may increase the neuromuscular blocking activities of Aclidinium. Amantadine, The therapeutic efficacy of Amantadine can 6385 - Phenanthroline | C12H8N2 | CAS No. 66-71.
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1,10-phenanthroline Regulatory process names 9 Translated names 22 CAS names 1 IUPAC names 8 Other identifiers 3 Print infocard Open Substance Regulatory Obligations

Ferroin is also used in the determination of other metals, such as nickel, ruthenium, and silver. 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. Inhibition of the enzyme occurs by removal and chelation of the metal ion required for catalytic activity, leaving an inactive apoenzyme. 1,10-Phenanthroline targets mainly zinc metallopeptidases, with a much lower affinity for calcium. 1,10-phenanthroline Regulatory process names 9 Translated names 22 CAS names 1 IUPAC names 8 Other identifiers 3 Print infocard Open Substance Regulatory Obligations 1,10-phenanthroline. 200-629-2. 66-71-7. Acute Tox. 3 Aquatic Acute 1 Aquatic Chronic 1.